The purpose of the present book is to provide chemical, metallurgical and materials scientists and engineers with uptodate corrosion data pertinent to academic studies and industrial problems resulting from the effects of pure molten salt and ashsalt deposit environments. The materials used in hightemperature structures have design constraints which are in addition to those on materials used at, or near to, room temperature. It also provides corrosion data essential for making the appropriate choices of candidate materials for hightemperature service in process conditions. The types o f damage include fuelash corrosion sulphates, including acid and basic fluxing reactions, and vanadic slag attack, molten salt corrosion chlorides, nitrates, and carbonates, and molten glass corrosion. Powder diffraction file pdf4 software provided the best match as a m3o4. High temperature corrosion studies in molten saltflinak. High temperature corrosion of inconel 600 in naclkcl molten salts article pdf available in advances in materials science and engineering 20142. This article examines the electrochemistry of such hot corrosion processes, focusing on sodium sulfate systems generated by the combustion of. To date there is a limited volume of work on the effects of mechanical stress on high temperature corrosion behaviour in molten salts. High temperature corrosion in molten salts free ebook download as pdf file. The results are interpreted using the nazoai203sio 2 ternary phase diagram, and some possible. Electrochemical monitoring of hightemperature moltensalt. Corrosion attack far more severe in molten fluoride salts than molten chloride salts 10 grain boundary attack was less severe in mgcl 2kcl contacted 800h in that the depth of voiding is less than compared to flinak exposed samples further investigation is needed to determine whether the lower weightloss of the 800h in the mgcl 2kcl.
Hightemperature corrosion tests were performed using both electrochemical polarization and immersion techniques. Introduction dissimilar metals are widely used in critical high service temperature applications. One of the first experiments proving this fact investigated commercial electrode thinning also called penciling, shown in figure 1, in high temperature. Work done previously has been done mostly to compare and evaluate the corrosion tendencies of materials by controlling one of the corrosion factors mentioned above 5. Intergranular corrosion of high temperature alloys in molten fluoride salts. University of wisconsin molten salt corrosion and flow loop experiments issues identified and path forward. High temperature corrosion of inconel 600 in naclkcl. Emerson engineers first address the problem by proposing a vanessa series 30,000 buttweld. High temperature molten salt corrosion in csp systems. The influences of air oxidation and molten salt environments on the hot corrosion behavior of the weldment have been discussed in this paper. Hot moltensalt corrosion can cause serious metal degradation in boiler plant, incinerators, and furnaces. Corrosion of structural alloys in molten salts for solar.
Hightemperature corrosion of uns n3 in molten li2bef4. For example, the corrosion of a gas turbine by a molten na 2 so 4 1, 2, 3 and the corrosion related to a molten carbonate fuel cell 4, 5 have been extensively investigated. This book provides engineers, physicists, and chemists with a balanced presentation of all relevant basic science and engineering aspects of hightemperature corrosion. Liquid metal attack is yet another special category. Molten salts are already used in concentrated solar power csp plants and studies have been conducted on the corrosion of metals in these salts 59. Corrosion in very hightemperature molten salt for next. Qualification of alloys for structural applications in. Corrosion behavior of nibased superalloys in molten. Pdf download high temperature corrosion free unquote books. Molten chloride salts for next generation concentrated. Castable cement can prevent moltensalt corrosion in csp. Influences of impurities it is well accepted that impurity levels tend to drive corrosion. University of wisconsin molten salt corrosion and flow loop experiments issues identified and path forward 1. Corrosion of molten salt thermal energy storage system containment materials is an important factor for system lifetime.
Hightemperature corrosion characteristics of yttriastabilized zirconia material in molten salts of liclli2o and liclli2oli. Qualification of alloys for structural applications in fluoride high temperature reactor fhr preet m. Corrosion resistance of mcralx coatings in a molten. Concentrating solar power csp technology often depends on molten salts to store and transport thermal energy from the sun during the day to generate electricity at night. Intergranular corrosion of high temperature alloys in. When choosing the composition of a salt for metal heat treatment, it is necessary to consider the corrosion activities of the molten salts in relation to the metal being heat treated. Effects of mechanical stress on high temperature corrosion. When compared with the depth of the corrosion products in kclk 2so 4 and naclna 2so 4, molten sylvite is more active than sodium. Corrosion activity of the molten bath can be decreased by strictly following the rules required for their operation, i.
Different types of hightemperature corrosion include. Many alloys used at high temperature in industrial processes are nibased and many others contain it in appreciable quantities, so it is of interest to evaluate the performance of pure nickel in order to determine the behavior of its alloys once the elements responsible for their protection have been depleted due to accelerated corrosion processes in the presence of vanadiumrich molten salts. Corrosion mechanisms in chloride and carbonate salts. Corrosion tests at 400, 500, and 680c were performed using four high temperature alloys 347ss, 321ss in625, and ha230. Corrosion and thermal stability of crmnfeni high entropy. Research article high temperature corrosion of inconel 600 in naclkcl molten salts g. Molten fluoride salts possess several important properties. High temperature corrosion in molten salts ion salt. This work utilizes the multimodal microscopy methods of synchrotron xray nanotomography and electron microscopy to investigate the 3d morphological and chemical evolution of two. Therefore, the studies on the corrosion of the structural materials for handling high temperature molten salts have also been continuously carried out.
The influence of cu content on high temperature corrosion behavior. Advanced hightemperature molten saltschlorides and carbonatesare efective for nextgeneration csp plants. Investigation was carried out using electrochemical techniques such as polarization curves, rest potential measurements, linear polarization resistance, and electrochemical impedance spectroscopy. Corrosion in very hightemperature molten salt for next generation. Fuelash or ashhaltdeposit corrosion stems from hightemperature. The microstructural evaluation and characterization of 316 stainless steel samples that were tested in molten li 2 bef 4 flibe salt were investigated in this study for evaluating its performance in hightemperature molten fluoride salts. The interaction of molten salts of different nazo activities and mullite is examined with furnace and burner tests. Handling high temperaturecorrosive molten salts is essential in alternative energy production. Research article high temperature corrosion of inconel 600. The key challenge involves a highly corrosivehigh temperature media i. High temperature studies on welded joint in molten salt. Recently, 316 stainless steel and flibe salt are being actively considered as the main structural alloy and primary coolant of fluoride saltcooled high. The primary corrosion mechanism for high strength alloys in molten chloride salts is the selective oxidation of cr the reaction mechanism for the selective oxidation of cr is mass transfer limited and it has been shown that corrosion occurs significantly faster in systems with convective flow.
Metals and ceramics exposed to hightemperature salt solutions are susceptible to a form of corrosion caused by fused salts accumulating on unprotected surfaces. High temperature corrosion resistance of different. Hightemperature corrosion behavior of superalloys in molten. Handling high temperaturecorrosive molten salts emerson us. Flow accelerated corrosion l high temperature oxidation m outside surface k hydrogen tritium related. Electrochemical study of corrosion in high temperature molten salts. Pdf high temperature corrosion of inconel 600 in nacl. Coated salt corrosion method, was used to study the corrosion behavior of a new type of heatresistant steel in a molten salt environment with. The moreacidic molten salts form small amounts of a1203. Low aluminum content in mcralxsbetween 5 and 12wt%is required to achieve a good balance between mechanical properties and hightemperature performance. Inhibiting steel corrosion when in contact with molten salts can help optimise materials for concentrated solar power technology and other hightemperature applications.
Numerous commercial processes operate at temperatures exceeding 500 degrees celsius. Hightemperature corrosion characteristics of yttria. In this research, electrochemicalimpedance and electrochemicalnoise techniques have been evaluated for the monitoring of hotcorrosion processes in such plants. Hightemperature corrosion is a mechanism of corrosion that takes place in gas turbines, diesel engines, furnaces or other machinery coming in contact with hot gas containing certain contaminants. The corrosion behavior of a516 carbon steel was evaluated to determine the effect of the dissolved chloride content in molten binary solar salt. Glossary of selected terms used in high temperature corrosion pages. Curves of corrosion current density vs temperature obtained by the potentiodynamic studies are reported, as well as. Growing interest in molten salts as effective hightemperature heattransfer fluids for sustainable energy systems drives a critical need to fundamentally understand the interactions between metals and molten salts. These important additional constraints include timedependent inelastic strain creep, thermal stability of the microstructure and hightemperature. This study presents a method for investigating the effects of mechanical stress on the high temperature corrosion behaviour in na 2 co 3 nacl and na 2 so 4 nacl eutectic salts. Identify molten saltmaterial combinations that have long service life and meet performance needs. The addition of these constraints to those of low cost, strength, toughness, machinability, formability, weldability, and combinations of these, has led to the intensive development, over the past 50 years, of an.
High temperature corrosion of nickel in navo3v2o5 melts. Steinberg, corrosion of inconel 601 in molten salts for. Fuel sometimes contains vanadium compounds or sulfates which can form compounds during combustion having a low melting point. Galetz high temperature corrosion in molten solar salts.
Kno 3 solar salt mixture on corrosion behavior of low. The mechanisms of molten product corrosion are complex. Characterize corrosion rates, corrosion mechanisms, and. It covers most htc types, including oxidation, sulfidation, nitridation, molten salts, fuelash corrosion, h2sh2 corrosion, molten fluoridehf corrosion, and carburization. Corrosion in very hightemperature molten salt for next generation csp systems. Introduction the department of energy doe is working with industry to develop a very high temperature. Tests have been carried out on ni1 % co and alloy 800, a commercial material of interest to operators of industrial plants. High temperature corrosion download ebook pdf, epub. By addition of the mg inhibitor, the corrosion rates of the studied alloys were found to be. High temperature corrosion in molten salts sequeira. Corrosion of metals by molten salts in heattreatment. A solution for molten nitrate salt corrosion in concentrated solar power plants solar energy materials and solar cells 146 2016, 815 a. Corrosion of high temperature alloys in solar salt at 400, 500, and. A simple method for the inhibition of the corrosion of.
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